Three submission methods[1]
In person: show documents at Service Canada. Online: upload digital copies in the official service. By mail: send the signed form and original documents to the SIN office.

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Service Canada / SIN / NAS / Free preparation
A SIN is a personal nine-digit number. Applying to Service Canada is free. Prepare a first application as a permanent resident here.
WHO THIS GUIDE IS FOR
First SIN: an adult permanent resident applying for themselves in Canada. This edition does not cover representatives, children, temporary-SIN updates or applications from abroad.
If you already have a SIN, do not apply as if it were your first. Status changes, temporary permits and applications for someone else need a different route.
In person: show documents at Service Canada. Online: upload digital copies in the official service. By mail: send the signed form and original documents to the SIN office.
NAS2120 is used for mail applications. You do not need this form when applying for yourself online or in person. Its fields are explained here to help prepare your information.
References support what you read here. You do not need to open them to complete the preparation steps.